Rubidium bromide

Rubidium bromide
Identifiers
CAS number 7789-39-1 Y
PubChem 4670918
ChemSpider 74217 Y
Jmol-3D images Image 1
Properties
Molecular formula RbBr
Molar mass 165.372 g/mol
Appearance white crystalline solid
Density 3.350 g/cm3
Melting point

693 °C, 966 K, 1279 °F

Boiling point

1340 °C, 1613 K, 2444 °F

Solubility in water 98 g/100 mL
Hazards
EU Index Not listed
Flash point Non-flammable
Related compounds
Other anions Rubidium fluoride
Rubidium chloride
Rubidium iodide
Other cations Lithium bromide
Sodium bromide
Potassium bromide
Caesium bromide
 Y (verify) (what is: Y/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Rubidium bromide is the bromide of rubidium. It has a NaCl crystal structure, with a lattice constant of 685 picometres. [1]

There are several methods for synthesising rubidium bromide. One involves reacting rubidium hydroxide with hydrobromic acid:

RbOH + HBr → RbBr + H2O

Another method is to neutralize rubidium carbonate with hydrobromic acid:

Rb2CO3 + 2HBr → 2RbBr + H2O + CO2

Rubidium metal would react directly with bromine to form RbBr, but this is not a sensible production method since rubidium metal is substantially more expensive than the carbonate or hydroxide; moreover, the reaction would be explosive.

References

  1. ^ G. Chern, J. G. Skofronick, W. P. Brug ,S. A. Safron (1989). "Surface phonon modes of the RbBr(001) crystal surface by inelastic He-atom scattering". Phys. Rev. B 39 (17): 12838–12844. doi:10.1103/PhysRevB.39.12838.